| Year (s) Served | Name | Chapter | City |
| Sis. Belle Hart | |||
| Sis. Sallie Harvey | |||
| 1901-1902 | Sis. Jennie Queen | Susannah No. 2 | Paducah, KY |
| 1903-1908 | Sis. Sallie Morton | Queen of South No. 54 | Paducah, KY |
| 1909-1913 | Sis. Ella Emery | Electa No. 19 | Middlesboro, KY |
| 1914-1915 | Sis. M.L. Freeman | Jepthah No. 17 | Paris, KY |
| 1916-1918 | Sis. Lillian Brown | ||
| 1919-1927 | Sis. Pearl Rankin | Phyllis Wheatley, No. 39 | Richmond, KY |
| 1928-1948 | Sis. Mayme L. Copeland | Progressive No. 63 | Hopkinsville, KY |
| 1948-1957 | Sis. Amy V. Stockton | Rose of Sharon No. 56 | Mt. Sterling, KY |
| 1957-1975 | Sis. Blanche W. Lewis | Allen No. 18 | Winchester, KY |
| 1975-1987 | Sis. Ovetta T. Basey | Mt. Pride No. 88 | Hazard, KY |
| 1987-2007 | Sis. Eleanor Kavanaugh | Phyllis Wheatley, No. 39 | Richmond, KY |
| 2007- | Sis. Wathetta A. Burford | Evening Star No. 126 | Bowling Green, KY |
