| Year Served | Name | Chapter | Home Town |
| 1895-1899 | Sis. Fannie Shannon | Mizpah No. 16 | Frankfort, KY |
| 1900-1901 | Sis. Nannie Slaughter | Winchester No. 18 | Georgetown , KY |
| 1901-1909 | Sis. Cecelia Dunlap | Hagar No. 10 | Earlington, KY |
| 1909-1910 | Sis. Emma B. Jackson | Deborah No. 1 | Lexington, KY |
| 1911-1913 | Sis. M.L. Freeman | Jephthah No. 17 | Paris, KY |
| 1914-1916 | Sis. Mayme Matlock | Queen Esther No. 4 | Paducah, KY |
| 1917-1922 | Sis. Mollie Williams | Golden No. 8 | Louisville, KY |
| 1923-1927 | Sis. Sarah E. Peppers | Dorcas No. 29 | Lexington, KY |
| 1928-1930 | Sis. Elizabeth B. Delaney | Kenton No. 40 | Covington, KY |
| 1931-1933 | Sis. Elizabeth P. Gordon | Aurora No. 96 | Louisville, KY |
| 1933-1935 | Sis. Amy V. Stockton | Rose of Sharon No. 56 | Mt. Sterling, KY |
| 1936-1937 | Sis. Bessie B. Ballard | Mizpah No. 16 | Frankfort, KY |
| 1938-1939 | Sis. Susie B. Williams | Naomi No. 6 | Hopkinsville, KY |
| 1940-1943 | Sis. Julia C. Parrish | Allen No. 18 | Winchester, KY |
| 1944-1954 | Sis. Annie Lee Moore | Celestine No. 9 | Danville, KY |
| 1946-1947 | Sis. Carrie A. Taylor | Zorah No. 20 | Louisville, KY |
| 1948-1949 | Sis. Mary Belle Jones | Dorcas No. 29 | Lexington, KY |
| 1950-1951 | Sis. Blanche W. Lewis | Allen No. 18 | Winchester, KY |
| 1952-1953 | Sis. Mary B. Howe | Burns No. 31 | Maysville, KY |
| 1954-1955 | Sis. Lavina L. Larkins | Golden No. 8 | Louisville, KY |
| 1956-1957 | Sis. Alpha Bynum | Aurora No. 96 | Louisville, KY |
| 1958-1959 | Sis. Annie Mae Jones | Kenton No. 40 | Covington, KY |
| 1960-1961 | Sis. Belle Stokes | White Rose No. 117 | Prospect, KY |
| 1962-1963 | Sis. Clara P. Bass | Burns No. 31 | Maysville, KY |
| 1964-1965 | Sis. Vivian G. Taylor | Allen No. 18 | Winchester, KY |
| 1966-1967 | Sis. Lillian B. Morris | Zorah No. 20 | Louisville, KY |
| 1968-1969 | Sis. Ovetta Basey | Mt. Pride No. 88 | Hazard, Kentucky |
| 1969-1970 | Sis. Hattie L. Taylor | White Rose No. 117 | Prospect, KY |
| 1971-1973 | Sis. Louise T. Bell | Progressive No. 63 | Hopkinsville, KY |
| 1973-1975 | Sis. Evelyn S. Burgess | Zorah No. 20 | Louisville, KY |
| 1975-1977 | Sis. Susie J. Ester | Rose of Sharon No. 56 | Mt. Sterling, KY |
| 1977-1979 | Sis. Geneva F. Jackson | Ruth No. 26 | Providence, KY |
| 1979-1981 | Sis. Willie Mae Taylor | Dorcas No. 29 | Lexington, KY |
| 1981-1983 | Sis. Eleanor Kavanaugh | Phyllis Wheatley No. 39 | Richmond, KY |
| 1983-1985 | Sis. Lottie B. Conner | Zorah No. 20 | Louisville, KY |
| 1985-1987 | Sis. Mollie M. Bradley | Alpha No. 90 | Midway, KY |
| 1987-1989 | Sis. Valerie Newsome | Queen Esther No. 4 | Paducah, KY |
| 1989-1991 | Sis. Margaret P. Gainer | Lilly White No. 132 | Fort Campbell, KY |
| 1991-1993 | Sis. Nadine S. Mason | Fairest No. 104 | Nicholasville, KY |
| 1993-1997 | Sis. Vanda L. Langham | Kenton No. 40 | Covington, KY |
| 1997-1999 | Sis. Ann E. Graves | Queen Vashti No. 37 | Georgetown, KY |
| 1999-2000 | Sis. Margaret Shanks | Rising Star No. 102 | Elizabethtown, KY |
| 2000-2003 | Sis. Donna Hawkins | Queen Esther No. 4 | Paducah, KY |
| 2003-2006 | Sis. Frances W. Wall | Lilly White No. 132 | Fort Campbell, KY |
| 2006-2009 | Sis. Pamela H. Thompson | Rose of Sharon No. 56 | Mt. Sterling, KY |
| 2009- | Sis. Betty J. Bell | Zorah No. 20 | Louisville, KY |
